Exfoliated graphite (EG) was prepared from commercially available natural graphite flakes (NGF), through strong acid treatment followed by thermal shock at 950 °C. The EG sheets were characterized with respect to their thermal stability via thermogravimetric analysis (TGA) and Raman spectra. Their morphology and particle size were evaluated using scanning electron microscope (SEM) and particle size analyzer. The potential of EG as reinforcement on the mechanical and thermal properties of the dynamically vulcanized polystyrene/styrene butadiene rubber (PS/SBR) composites was evaluated. The influence of EG on the electrical properties of the composites was measured as well.

References

1.
Coran
,
A. Y.
,
1988
,
Handbook of Elastomers
,
A. K.
Bhowmick
, and
H. L.
Stephens
, eds.,
Marcel & Dekker
,
New York
, p.
249
.
2.
Mehrabzadeh
,
M.
, and
Delfan
,
N.
,
2000
, “
Thermoplastic Elastomers of Butadiene-Acrylonitrile Copolymer and Polyamide. VI. Dynamic Crosslinking by Different Systems
,”
J. Appl. Polym. Sci.
,
77
(
9
), pp.
2057
2066
.
3.
Mousa
,
A.
,
Ishaiku
,
U. S.
, and
Mohd Ishak
,
Z. A.
,
2000
, “Rheological Properties of Dynamically Vulcanized Poly(Vinyl Chloride)/Epoxidized Natural Rubber Thermoplastic Elastomers: Effect of Processing Variables,”
Polym. Test.
,
19
(
2
), pp.
193
204
.
4.
Mousa
,
A.
,
Heinrich
,
G.
,
Simon
,
F.
,
Wagenknecht
,
U.
,
Stöckelhuber
,
K.-W.
, and
Dweri
,
R.
,
2012
, “Carboxylated Nitrile Butadiene Rubber/Hybrid Filler Composites,”
Mater. Res.
,
15
(
4
), pp.
671
678
.
5.
Mousa
,
A.
,
Heinrich
,
G.
, and
Wagenknecht
,
U.
,
2008
, “The Potential of O-MMT as a Reinforcing Filler for Uncured and Dynamically Cured PVC/XNBR Composites,”
J. Macromol. Sci., Part A: Pure Appl. Chem.
,
45
(
9
), pp.
733
741
.
6.
Mousa
,
A.
,
Ishiaku
,
U. S.
, and
Ishak
,
Z. A. M.
,
1999
, “Dynamic Vulcanisation of Poly(Vinyl Chloride)−Epoxidised Natural Rubber Thermoplastic Elastomers,”
Plast., Rubber Compos.
,
28
(
6
), pp.
288
295
.
7.
Li
,
J. H.
,
Liu
,
Q.
, and
Da
,
H. F.
,
2007
, “Preparation of Sulfur-Free Exfoliated Graphite at a Low Exfoliation Temperature,”
Mater. Lett.
,
61
(8–9), pp.
1832
1834
.
8.
Kang
,
F. Y.
,
Zheng
,
Y. P.
,
Wang
,
H. N.
,
Nishi
,
Y.
, and
Inagaki
,
M.
,
2002
, “Effect of Preparation Conditions on the Characteristics of Exfoliated Graphite,”
Carbon
,
40
(
9
), pp.
1575
1581
.
9.
Zheng
,
W.
, and
Wong
,
S. C.
,
2003
, “
Electrical Conductivity and Dielectric Properties of PMMA/Expanded Graphite Composites
,”
Compos. Sci. Technol.
,
63
(
2
), pp.
225
235
.
10.
Chen
,
G. H.
,
Wu
,
D. J.
,
Weng
,
W. G.
,
He
,
B.
, and
Yan
,
W. I.
,
2001
, “
Preparation of Polystyrene–Graphite Conducting Nanocomposites Via Intercalation Polymerization
,”
Polym. Int.
,
50
(
9
), pp.
980
985
.
11.
Li
,
Y.
,
2007
, “
Processing of Nano Graphene Plates (NGPs) and NGP Nanocomposite
,”
Master thesis
, Lanzhou University of Technology, Lanzhou, China.https://etd.ohiolink.edu/rws_etd/document/get/wright1176430617/inline
12.
Mousa
,
A.
, and
Karger-Kocsis
,
J.
,
2002
, “
Cure Characteristics of a Vinyl Ester Resin as Assessed by Ftir and Dsc Techniques
,”
Polym. Polym. Compos.
,
8
(
7
), pp.
455
460
.https://www.researchgate.net/publication/285666907_Cure_characteristics_of_a_vinyl_ester_resin_as_assessed_by_FTIR_and_DSC_techniques
13.
Ismail
,
H.
,
Mohamad
,
Z.
, and
Abu Bakar
,
A.
,
2004
, “
The Effect of Dynamic Vulcanization on Properties of Rice Husk Powder Filled Polystyrene/Styrene Butadiene Rubber Blends
,”
Iran. Polym. J.
,
13
(
1
), pp.
11
19
.http://en.journals.sid.ir/ViewPaper.aspx?ID=12576
14.
Wu
,
X.
,
Qi
,
S.
,
He
,
J.
, and
Duan
,
G.
,
2010
, “High Conductivity and Low Percolation Threshold in Polyaniline/Graphite Nanosheets Composites,”
J. Mater. Sci.
,
45
(
2
), p. 483.
15.
Lin
,
H. F.
,
Lu
,
W.
, and
Chen
,
G. H.
,
2007
, “Nonlinear DC Conduction Behavior in Epoxy Resin/Graphite Nanosheets Composites,”
Physica B
,
400
(1–2), pp.
229
–236.
16.
Jeong
,
H.-K.
,
Lee
,
Y. P.
,
Lahaye
,
R. J. W. E.
,
Park
,
M.-H.
,
An
,
K. H.
,
Kim
,
I. J.
,
Yang
,
C.-W.
,
Park
,
C. Y.
,
Ruoff
,
R. S.
, and
Lee
,
Y. H.
,
2008
, “Evidence of Graphitic AB Stacking Order of Graphite Oxides,”
J. Am. Chem. Soc.
,
130
(
4
), pp.
1362
–1366.
17.
Chen
,
G.
,
Weng
,
W.
,
Wu
,
D.
,
Wu
,
C.
,
Lu
,
J.
, and
Wang
,
P.
,
2004
, “Preparation and Characterization of Graphite Nanosheets From Ultrasonic Powdering Technique,”
Carbon
,
42
(
4
), pp.
753
759
.
18.
Zheng
,
W.
,
Wong
,
S.-C.
, and
Sue
,
H.-J.
,
2002
, “
Transport Behavior of PMMA/Expanded Graphite Nanocomposites
,”
Polymer
,
43
(25), pp.
6767
6773
.
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