Exfoliated graphite (EG) was prepared from commercially available natural graphite flakes (NGF), through strong acid treatment followed by thermal shock at 950 °C. The EG sheets were characterized with respect to their thermal stability via thermogravimetric analysis (TGA) and Raman spectra. Their morphology and particle size were evaluated using scanning electron microscope (SEM) and particle size analyzer. The potential of EG as reinforcement on the mechanical and thermal properties of the dynamically vulcanized polystyrene/styrene butadiene rubber (PS/SBR) composites was evaluated. The influence of EG on the electrical properties of the composites was measured as well.
Issue Section:
Research Papers
References
1.
Coran
, A. Y.
, 1988
, Handbook of Elastomers
, A. K.
Bhowmick
, and H. L.
Stephens
, eds., Marcel & Dekker
, New York
, p. 249
.2.
Mehrabzadeh
, M.
, and Delfan
, N.
, 2000
, “Thermoplastic Elastomers of Butadiene-Acrylonitrile Copolymer and Polyamide. VI. Dynamic Crosslinking by Different Systems
,” J. Appl. Polym. Sci.
, 77
(9
), pp. 2057
–2066
.3.
Mousa
, A.
, Ishaiku
, U. S.
, and Mohd Ishak
, Z. A.
, 2000
, “Rheological Properties of Dynamically Vulcanized Poly(Vinyl Chloride)/Epoxidized Natural Rubber Thermoplastic Elastomers: Effect of Processing Variables,” Polym. Test.
, 19
(2
), pp. 193
–204
.4.
Mousa
, A.
, Heinrich
, G.
, Simon
, F.
, Wagenknecht
, U.
, Stöckelhuber
, K.-W.
, and Dweri
, R.
, 2012
, “Carboxylated Nitrile Butadiene Rubber/Hybrid Filler Composites,” Mater. Res.
, 15
(4
), pp. 671
–678
.5.
Mousa
, A.
, Heinrich
, G.
, and Wagenknecht
, U.
, 2008
, “The Potential of O-MMT as a Reinforcing Filler for Uncured and Dynamically Cured PVC/XNBR Composites,” J. Macromol. Sci., Part A: Pure Appl. Chem.
, 45
(9
), pp. 733
–741
.6.
Mousa
, A.
, Ishiaku
, U. S.
, and Ishak
, Z. A. M.
, 1999
, “Dynamic Vulcanisation of Poly(Vinyl Chloride)−Epoxidised Natural Rubber Thermoplastic Elastomers,” Plast., Rubber Compos.
, 28
(6
), pp. 288
–295
.7.
Li
, J. H.
, Liu
, Q.
, and Da
, H. F.
, 2007
, “Preparation of Sulfur-Free Exfoliated Graphite at a Low Exfoliation Temperature,” Mater. Lett.
, 61
(8–9), pp. 1832
–1834
.8.
Kang
, F. Y.
, Zheng
, Y. P.
, Wang
, H. N.
, Nishi
, Y.
, and Inagaki
, M.
, 2002
, “Effect of Preparation Conditions on the Characteristics of Exfoliated Graphite,” Carbon
, 40
(9
), pp. 1575
–1581
.9.
Zheng
, W.
, and Wong
, S. C.
, 2003
, “Electrical Conductivity and Dielectric Properties of PMMA/Expanded Graphite Composites
,” Compos. Sci. Technol.
, 63
(2
), pp. 225
–235
.10.
Chen
, G. H.
, Wu
, D. J.
, Weng
, W. G.
, He
, B.
, and Yan
, W. I.
, 2001
, “Preparation of Polystyrene–Graphite Conducting Nanocomposites Via Intercalation Polymerization
,” Polym. Int.
, 50
(9
), pp. 980
–985
.11.
Li
, Y.
, 2007
, “Processing of Nano Graphene Plates (NGPs) and NGP Nanocomposite
,” Master thesis
, Lanzhou University of Technology, Lanzhou, China.https://etd.ohiolink.edu/rws_etd/document/get/wright1176430617/inline12.
Mousa
, A.
, and Karger-Kocsis
, J.
, 2002
, “Cure Characteristics of a Vinyl Ester Resin as Assessed by Ftir and Dsc Techniques
,” Polym. Polym. Compos.
, 8
(7
), pp. 455
–460
.https://www.researchgate.net/publication/285666907_Cure_characteristics_of_a_vinyl_ester_resin_as_assessed_by_FTIR_and_DSC_techniques13.
Ismail
, H.
, Mohamad
, Z.
, and Abu Bakar
, A.
, 2004
, “The Effect of Dynamic Vulcanization on Properties of Rice Husk Powder Filled Polystyrene/Styrene Butadiene Rubber Blends
,” Iran. Polym. J.
, 13
(1
), pp. 11
–19
.http://en.journals.sid.ir/ViewPaper.aspx?ID=1257614.
Wu
, X.
, Qi
, S.
, He
, J.
, and Duan
, G.
, 2010
, “High Conductivity and Low Percolation Threshold in Polyaniline/Graphite Nanosheets Composites,” J. Mater. Sci.
, 45
(2
), p. 483.15.
Lin
, H. F.
, Lu
, W.
, and Chen
, G. H.
, 2007
, “Nonlinear DC Conduction Behavior in Epoxy Resin/Graphite Nanosheets Composites,” Physica B
, 400
(1–2), pp. 229
–236.16.
Jeong
, H.-K.
, Lee
, Y. P.
, Lahaye
, R. J. W. E.
, Park
, M.-H.
, An
, K. H.
, Kim
, I. J.
, Yang
, C.-W.
, Park
, C. Y.
, Ruoff
, R. S.
, and Lee
, Y. H.
, 2008
, “Evidence of Graphitic AB Stacking Order of Graphite Oxides,” J. Am. Chem. Soc.
, 130
(4
), pp. 1362
–1366.17.
Chen
, G.
, Weng
, W.
, Wu
, D.
, Wu
, C.
, Lu
, J.
, and Wang
, P.
, 2004
, “Preparation and Characterization of Graphite Nanosheets From Ultrasonic Powdering Technique,” Carbon
, 42
(4
), pp. 753
–759
.18.
Zheng
, W.
, Wong
, S.-C.
, and Sue
, H.-J.
, 2002
, “Transport Behavior of PMMA/Expanded Graphite Nanocomposites
,” Polymer
, 43
(25), pp. 6767
–6773
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